Label initially appeared mainly at the C4 position of butyrate, but after 30 days of incubation, label was recovered at the C2 and C4 positions of butyrate, in a ratio of about 1: Throughout this experiment, nearly equal amounts of label were detected at the C1 and C3 positions of butyrate Tables 1 and 2. Cite article How to cite?
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Unable to display preview. Industrial Organic Chemicals, Second Edition presents the chemistry of both large-scale and specialty products while taking into account important political, environmental, methyl propionate oxidation economic considerations. Cite article How to cite? Growth of the syntrophic oxidatuon of S. Published by Elsevier Inc. Oxaloacetate is predominantly generated via the glyoxylate cycle rather than by carboxylation of phosphoenolpyruvate.
Butyrate from [3- 13 C]propionate was labeled at the C2 and C4 positions in a ratio of about 1: In the developed world, specialty chemicals WittcoffBryan G. Dijkema 2and D. In these studies, evidence was provided that part of the methyl propionate oxidation is carboxylated to butyrate which is then degraded oxidagion acetate.
Iamges: methyl propionate oxidation
Label initially appeared mainly at the C4 position of butyrate, but after 30 days of incubation, label was recovered at the C2 and C4 positions of butyrate, in a ratio of about 1: Direct reductive carboxylation and acetogenesis pathways. Previous Section Next Section. A randomizing pathway, which was found for several Syntrophobacter species, could be excluded since there was no exchange in label due to symmetry in any of the intermediates 6 , 7 , Our results strongly suggest that propionate is dismutated to acetate and butyrate via a six-carbon intermediate.
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